Synthesis of bicyclo[2.2.2]octadiene-fused 5,15-diazaporphyrin and 10-azacorrole with meso-imine bridges

Tetsuo Okujima, Yuki Ueda, Manami Inoue,Shigeki Mori,Keishi Ohara,Masayoshi Takase,Hidemitsu Uno,Toshio Naito

Journal of Porphyrins and Phthalocyanines（2022）

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摘要

Bicyclo[2.2.2]octadiene(BCOD)-fused 5,15-diazaporphyrins were synthesized via a metal-template aza-annulation of dipyrrin-metal complexes as a soluble precursor of tetrabenzodiazaporphyrin. 10-Azacorrole copper complex with a meso-imine bridge was serendipitously obtained via the same reaction using dimethylBCOD-fused dipyrrin-copper complex.

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5,15-diazaporphyrin,10-azacorrole

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