Geopolymerization Kinetics of Steel Slag Activated Gasification Coal Fly Ash: A Case Study for Amorphous-Rich Slags

The geopolymer processing of amorphous-rich slag required excessive soluble alkali usage severely limiting the application of geopolymer materials. In this study, industrial solid waste steel slag (SS) was introduced as alkali substitution for stimulating the potential activity of Shell gasification coal fly ash (SFA). Result shows that a 15%-20% addition of SS can reduce 14.5-23.3% NaOH consumption for the preparation of high-strength geo-polymers. SS accelerates the dissolution rate of SFA promoting the early strength of geopolymer (ES) via alka-linity adjustment and reducing the wetting angle of refactoring globular particles in the slurry. The long-term strength of geopolymer (LS) is increased to 68.5 MPa with the higher devotion of SFA (67 omega%). During the geopolymerization course, Ca-rich hydrates growth are competed with the polymerization of amorphous min-erals. The geopolymerization kinetics enlightens that the soluble tetrahedral SiO4 or AlO4 and hydrates in pozzolanic phase initially generated in paste then transformed to a more stable form of amorphous phase after a series of repeated processes of dissolution, homogeneous nucleation, and heterogeneous growth. This work paves a environmentally friendly way for disposing amorphous-rich slags with low activity and discloses the detailed mechanism of related geopolymerization.