Inorganic geochemistry of saline substrates associated with coastal turf, Otago Peninsula, New Zealand

Halophytic plant communities have developed on exposed coastal landforms to form low-stature turf in several locations around New Zealand. We quantify the inorganic geochemistry, mineralogy and simulated ephemeral surface water composition of saline soil-free bare ground at a well-preserved site at Maori Head on Otago Peninsula, where halophytes have colonised from adjacent coastal turf. The community at this site is dominated by Leptinella dioica, Samolus repens, Disphyma australe and Selliera radicans. Maori Head substrates are dominated by clay-altered basalt colluvium and show a general trend from high electrical conductivity (EC > 10 mS/cm) and weakly acid pH (< 6) on bare ground to low EC (< 1 mS cm(-1)) and higher pH (> 7) in turf and adjacent pasture soils. High salinities on dry substrates and in simulated ephemeral surface waters result from surface evaporation of airborne sea spray and contain halite (NaCl) with some gypsum (CaSO4.2H(2)O). Chemical interactions with the substrate are minor. The high surface salinities were maintained despite a major winter rain event with strong onshore winds. However, surface salinity is frequently leached by rain and shallow groundwater, whereas inland saline sites (pH 8-11) have substantial salt accumulations driven by lower rainfall, high evaporation and chemical interaction with Otago Schist-derived substrates.