1,7-, 1,6-, and 1,6,7- Derivatives of dodecylthio perylene diimides: Synthesis, characterization, and comparison of electrochemical and optical properties
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY(2023)
摘要
•Three derivatives of dodecylthio substituted perylene diimides are characterized.•Changes in the substitution pattern affect the photo-physical and electrochemical properties.•The magnitude of ground to excited-state dipole moment varies between derivatives.•The color of reduced forms highlight their potential use as electrochromic materials.
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关键词
Perylene diimides,Dipole Moment,regioisomers,Density functional theory,Lippert-Mataga
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