Ultra-fast Surface Reconstruction Enabled by the Built-in Electric Field in Heterostructured CoS2/CuS for Water Electrolysis

Transition-metal chalcogenides (TMCs) show great potential as highly efficient and cost-effective electrocatalysts for oxygen evolution reaction (OER). Yet the electrochemical conversion into oxides/ hydroxides remains poorly understood. In this work, we develop a built-in, electric-field-induced surface reconstruction strategy for ultra-fast self-activation of transition metal sites in self-supporting CoS2/CuS heterostructures. The activated CoS2/CuS grown on carbon cloth with oxygenated surface species displays an outstanding OER electrocatalytic activity with ultra-low overpotentials of only 136 mV at the current density of 10 mA cm(-2) and 266 mV at 100mA cm(-2) in 1.0MKOH. Comparative studies via synchrotron radiation X-ray absorption spectroscopy and theoretical calculations are employed to elucidate that the built-in electric field within heterointerfaces significantly promotes the reconstruction efficiency by decreasing the formation energy of (oxy) hydroxide species. We believe this work provides new perspectives to conceive catalysts with ultra-low overpotentials and complements the fundamental comprehension of TMCs' self-reconstruction mechanism.