Self-assembly of Thiolato-Bridged Ester-Functionalized Re(i)-based Tetranuclear Spiro-Metallacyclophanes

Jisna Varghese,Udit Kumar,Shilpa Jose,Aamir Afzal Magray,S. Yeswanth Kumar,R. Padmanaban,Bala Manimaran

New journal of chemistry（2023）

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摘要

Rhenium(i) based sulfur-bridged tetranuclear spiro-metallacyclophanes of M4S2L-type were obtained via oxidative addition of diaryl disulfide to rhenium carbonyl with the simultaneous coordination of the pyridyl moiety of tetradentate ptpc ligand.

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