Electricity-Promoted Friedel-Crafts Acylation of Biarylcarboxylic Acids.
The Journal of organic chemistry(2023)
摘要
An electricity-promoted method for Friedel-Crafts acylation of biarylcarboxylic acids is described in this research. Various fluorenones can be accessed in up to 99% yields. During the acylation, electricity plays an essential role, which might motivate the chemical equilibrium by consuming the generated TFA. This study is predicted to provide an avenue to realize Friedel-Crafts acylation in a more environmentally friendly process.
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关键词
biarylcarboxylic acids,friedel–crafts acylation,electricity-promoted
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