Non-flammable Phosphate-Grafted Nanofiber Separator Enabling Stable-Cycling and High-Safety Lithium Metal Batteries
JOURNAL OF THE ELECTROCHEMICAL SOCIETY(2023)
摘要
Lithium metal batteries (LMBs) are promising rechargeable energy storage devices with high energy densities and long lifetimes. Nevertheless, safety concerns constitute a severe impediment to the commercial demand for LMBs, including uncontrollable lithium dendrites, heat-intolerant separators, and flammable electrolytes. Herein, a novel separator (PSVHM) containing poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), poly(methyl methacrylate) (PMMA) and cage silsesquioxanes, phosphorous-containing acrylate monomers is fabricated by electrospinning with in situ ultraviolet-irradiation grafting polymerization. Attributed to the presence of phosphate groups in the membrane with flame retardant properties, the PSVHM separators have outstanding self-extinguish capabilities. In addition, the 3D-crosslinked PSVHM separator possesses high ion conductivity, and excellent mechanical strength, thus suppressing the uneven lithium dendrites and constructing a stable solid electrolyte interface (SEI). Moreover, cell assembled with the PSVHM separator exhibits an ultra-capacity retention of 98% after 200 cycles at a high current density of 2 C. This work provides a guideline for the preparation of high-safety and high-performance lithium metal batteries.
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关键词
Rechargeable Batteries,Battery Materials,Flexible Supercapacitors,Lithium-Sulfur Batteries,Polymer Electrolytes
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