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Pursuing High Efficiency in Photocatalytic Oxidative Couplings of Heteroarenes and Aliphatic C–H Bonds

Luoqiang Zhang,Dao-Yong Zhu,Jingyao Hu,Minjun Feng,Tze Chien Sum,Haoran Sun,Hajime Hirao, Yonggui Robin Chi,Jianrong Steve Zhou

Organic chemistry frontiers（2023）

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Abstract
Azole and azine heteroarenes were directly alkylated by alkanes, ethers, or carbamates using PhC(O)O2tBu under LED irradiation. 9,10-Dichloroanthrocene acted as an organic photocatalyst and transferred its excitation energy to PhC(O)O2tBu via exciplex formation.
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