铜催化不饱和化合物硅加成反应的研究进展

Organosilicons are not only very useful functional molecules, but also important organic synthetic intermediates. It could be easily transformed into many other useful functional compounds under various conditions. So far, a lot of transition metal-catalyzed methods have been developed to prepare organosilicon compounds. Among them, copper-catalyzed silyl addition reactions to unsaturated compounds are extremely important for the synthesis of organosilicon compounds. Herein, the recent research progress in the synthesis of organosilicons by copper-catalyzed silyl addition of silyl reagents to diverse unsaturated compounds such as alpha,beta-unsaturated carbonyl compounds, imines, Morita-Baylis-Hillman (MBH) alcohols, p-quinone methides, alpha,beta-unsaturated alkyne carbonyl compounds and alpha,beta-unsaturated sulfones is summarized. It will largely promote the development of such copper-catalyzed silyl addition reactions.