Sodium-iodide-promoted Nickel-Catalyzed C–N Cross-Coupling of Aryl Chlorides Andn-Nucleophiles under Visible-Light Irradiation

Sodium iodide facilitates halogen exchange in single nickel photocatalysis, which is critical to achieve C–N couplings of aryl chlorides and diverse nitrogen nucleophiles under visible-light irradiation in the absence of an exogenous photocatalyst.