Optimization of synthesis conditions, characterization and magnetic properties of lanthanide metal organic frameworks from Brønsted acidic ionic liquid
Journal of Molecular Structure(2023)
摘要
•Two new two dimensional metal organic frameworks namely {Er2[(C9N2O4H11)3·H2O·Br]Br·Cl}n (1) and {Yb2[(C9N2O4H11)3(H2O)2]Br·Cl2}n (2) were solvothemally synthesized with Brønsted ionic liquid as ligand.•The effects of the reaction conditions to the growth of 1 and 2, such as temperature, reaction solvents, as well as the ratio of solvents were explored.•1 and 2 display good thermal stability and hydrophilicity in this work.•The magnetic measure of 2 shows its antiferromagnetic interaction via the Yb/O-C-O/Yb pathways.
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关键词
Metal organic frameworks,Ionic liquid,X-ray single crystal diffraction,Magnetic property
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