Kinetic study of the azo – hydrazone photoinduced mechanism in complexes with a -Re(CO)3L0/+ core by flash photolysis

Tamara Maldonado,Erick Flores,Alejandra Gómez,Fernando Godoy,Carolina Mascayano,Angel A. Martí,Guillermo Ferraudi

Journal of Photochemistry and Photobiology A: Chemistry（2023）

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摘要

•Re(I)-azo/hydrazone complexes were studied by flash photolysis and DFT calculations.•Fast photoinduced E → Z isomerization with a thermal back reaction mediated by tautomerization.•Isomerization/tautomerization for Re(I)-azo/hydrazone occur by different mechanisms.•Azo group in the Re(I) complexes produce a high degree of MO mixing.

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关键词

Rhenium complexes,Tautomerism,Isomerization,Flash photolysis

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