Molecular Rotation Induced Giant, Anisotropic Negative Thermal Expansion in a Hydrogen-Bonded Coordination Framework

Peng Meng,Aidan Brock,Xiaodong Wang,Yuting Wang,John McMurtrie,Jingsan Xu

INORGANIC CHEMISTRY FRONTIERS（2023）

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摘要

We report a new supramolecular structure of cyanuric acid–melamine–zinc (CA–M–Zn) demonstrating unique molecular rotation induced negative thermal expansion along the c axis, accompanied by a significant decrease of β angle (−3.8%).

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Negative Thermal Expansion

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