New asymmetric AB3-type free-base and metalloporphyrin-cyclotriphosphazene conjugates: Synthesis and photophysical-photochemical properties

Kevser Harmandar,Tuğba Küçük,Emel Önal,Hanife İbişoğlu,Devrim Atilla,Şule Şahin Ün

INORGANICA CHIMICA ACTA（2023）

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摘要

•Novel asymmetric metal free, Zn(II) and Pd(II) porphyrin derivatives were synthesized.•Photophysico-chemical properties of these porphyrin derivatives were studied.•Compound 5 has the highest singlet oxygen quantum yield due to the heavy metal effect of Pd(II).

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关键词

Cyclotriphosphazene,Porphyrin,Photochemical,Photophysical properties,Zinc (II),Palladium (II)

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