One pot synthesis of carbon decorated NiO nanorods as cathode materials for high-performance asymmetric supercapacitors
JOURNAL OF ENERGY STORAGE(2023)
摘要
The composites of metal oxides and carbons are of research interest for improving the energy density of supercapacitors. In this work, we have demonstrated a simple one-pot hydrothermal synthesis method to prepare NiO nanorods followed by carbon framework decorated NiO nanorods (NiO@C). The NiO@C electrode showed an excellent specific capacitance of 1360 F g-1 compared to pristine NiO of 890 F g-1 at 1 A g-1 in a voltage range of 0.05 to 0.5 V in 1 M KOH electrolyte. The NiO@C electrodes showed excellent cycle stability over 10,000 cycles with 90 % capacitance retention. Asymmetric supercapacitors fabricated using corncob-derived activated carbon anode, and NiO@C cathode delivers a power density of 4574 W kg- 1 at an energy density of 21.6 Wh kg- 1. The enhanced capacitance of NiO@C material is due to the synergistic effect of the pseudocapacitive of NiO nanorods and the electric double-layer capacitance of the carbon matrix. Besides, the carbon framework facilitates quick charge acceptance, improved cycling stability, and rate capability. The cost-effective one-pot synthesis and eco-friendly NiO nanorods with easy electrode fabrication open opportunities for developing high-energy-density NiO-based supercapacitors.
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关键词
NiO@C nanorods,Activated carbon,Asymmetric supercapacitor,Electrochemical performance,Energy density,Power density
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