Progressive Formation of Active and Stable Ptzn Bimetallic Nanoclusters by Exsolution During Propane Dehydrogenation

SSRN Electronic Journal(2023)

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摘要
•2D zincosilicate support was prepared by delamination of layered MWW precursor.•PtZn bimetallic sites were formed by exsolution of Zn from the support during PDH.•High propane conversion comparable to the thermodynamic equilibrium was obtained.•Extraordinary stability with a low deactivation rate (kd < 0.002 h−1) was obtained.
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关键词
PtZn, Exsolution, Propane, Dehydrogenation, DML, Zeolites
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