Application of a ferrocene-chelating heteroscorpionate ligand in nickel mediated radical polymerization

Shuangshuang Li,Ashton Davis,Hootan Roshandel, Nima Adhami,Yi Shen, Nathalie H Co, Leo Morag, Hafez Etemad,Yuan Liu,Paula L. Diaconescu

Inorganic Chemistry Frontiers（2024）

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摘要

A nickel bromide complex supported by a non-innocent ferrocene-chelating heteroscorpionate ligand, [(fc(PPh2)(BH(3,5-Me2pz)2)NiBr] ((fcP,B)NiBr, fc = 1,1’-ferrocenediyl, pz = pyrazole), was synthesized and characterized. The compound can be readily oxidized according...

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