Furoyl peroxynitrate (fur-PAN), a product of VOC–NO_x photochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations

James M. Roberts,J. Andrew Neuman, Steven S. Brown, Patrick R. Veres, Matthew M. Coggon,Chelsea E. Stockwell, Carsten Warneke,Jeff Peischl,Michael A. Robinson

Environmental Science: Atmospheres（2022）

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摘要

Wildfires produce furan compounds that are involved in atmospheric oxidant and SOA formation. One such compound, furfural, produces furoyl peroxynitrate (fur-PAN) in the atmosphere, a unique marker for this wildfire chemistry.

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Furoyl peroxynitrate (fur-PAN), a product of VOC–NOx photochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations

Furoyl peroxynitrate (fur-PAN), a product of VOC–NO_x photochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations