Stannyl radical-mediated synthesis of 6H-1,3-oxazin-6-ones from 2-acyloxyazirines or whether free radicals can open the azirine ring?

Organic Chemistry Frontiers(2022)

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摘要
Stannyl radicals initiate a radical cascade reaction of 2-acyloxyazirines, the acyloxy group of which ensures the irreversibility of the ring cleavage and controls the switching of the reaction outcome between 1,3-oxazin-6-ones and oxazoles.
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