Study of the interaction between NH3 and NO in the reduction zone of air-staged ammonia combustion under high moisture atmosphere

NH3 is used as a hydrogen-rich fuel, and the water vapor content produced by combustion can reach 30%. However, high NOx emission is one of the main problems restricting its application. The air-staged combustion is an effective low-NOx combustion strategy, subdividing the combustion process into three typical sections: the main combustion zone, the reduction zone, and the burnout zone. Fully utilizing the reaction between NH3 and NO in the reduction zone is expected to achieve an effective control of NOx emission. This research aims to explore the reduction ability of the residual NH3 on NO reduction in the reduction zone under high moisture atmosphere formed by ammonia combustion. An isothermal flow reactor was used to study the kinetic characteristics of the NH3/NO reaction under no-oxygen or residual low-oxygen condition in a wide temperature range (1073-1773K) and a high water vapor content range (0-50%). Additionally, three chemical kinetic models were used in simulations. The results showed that oxygen significantly changes the effect of water vapor on the NH3/NO reaction. In the absence of oxygen, water vapor has less effect on NH3/NO reaction at lower temperatures (<1500K). In the presence of oxygen, the increase of water vapor content leads to a significant shift of the reaction temperature window to higher temperatures and a decrease of the maximum NO reduction efficiency. Finally, the remarks about using residual NH3 to complete NOx removal in ammonia combustion were discussed.