Tribological Behavior and Wear Protection Ability of Graphene Additives in Synthetic Hydrocarbon Base Stocks

Graphene carbon materials show good tribological properties due to their unique layered structures. In this work, the tribological properties of graphene (GN) and fluorinated graphene (FGN) were studied in two kinds of synthetic hydrocarbon base stocks at different working conditions. Firstly, the structures of GN and FGN were characterized comparatively using FT-IR, Raman, XRD, and TGA. Secondly, the tribological properties of GN and FGN as the lubrication additives both in PAO6 and CTL6 were studied on a four-ball tester. Finally, the surfaces of friction counterparts, before and after tribological tests, were analyzed to disclose the lubrication mechanism using UV, micro-Raman, and EDS. The results show that GN and FGN can be stably dispersed in the selected synthetic hydrocarbon base stocks with 1 wt.% T161 as the dispersant, and the optimal addition of graphene additive is 100 ppm, which shows better friction reducing and anti-wear properties. GN and FGN also show better tribological performance at a higher load (not less than 392 N), and their compatibility with PAO6 is better. The worn surface analysis shows that the graphene additive participates in the lubrication film formation during friction by frictional chemical reaction with friction counterparts, which could improve the stability and tribological performance, resulting in an increased application temperature of synthetic hydrocarbon base stock by at least 10 degrees C.