An improved volume translation model for PC-SAFT EOS based on a distance function

Chemical Engineering Science（2023）

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摘要

•A novel distance-dependent volume translation is introduced into PC-SAFT EOS.•The volume-translated PC-SAFT model reproduces critical properties of pure compounds.•Accurate property predictions of pure compounds are achieved over a wide range of T/P.•A generalized volume-translated PC-SAFT EOS is proposed for n-alkanes.

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关键词

Volume translation,Distance function,PC-SAFT EOS,Density prediction,Thermodynamic consistency

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