A Study of Biochar Physiochemistry and Particle Size Distribution Influencing the Properties of Water-Based Slurry Fuels.

Biochar-based slurry is a fossil-free-liquid fuel derived from a renewable source, biomass. This study aims to examine the properties of this fuel as an alternative to coal-water slurries. The slurries were produced by suspending 40 wt% biochar in a solution made of water and a surfactant. Two biochar types from chemically treated and untreated rice straw (RS) were utilized to assess the impact of particle-particle interactions and biochar physicochemical composition on slurry properties, including stability, rheology, and heating value. Additionally, three particle size distributions (PSD), two unimodal and a bimodal, were used to analyze the effect of PSD on the abovementioned properties.All slurries had an average energy content of 7.32 & PLUSMN; 0.27 MJ/kg. The stability of the slurry was higher for fine particles from treated RS with unimodal PSD (Dv50 8.8 & PLUSMN; 0.68 & mu;m). However, slurries containing fine and coarse particles with bimodal PSD (Dv50 15.8 & PLUSMN; 0.64 & mu;m) had relatively lower apparent viscosities of 342.1 and 336.55 mPa.s at a shear rate of 100 s-1 for slurries made of biochar from treated and untreated RS, respectively. Slurries containing coarse particles from treated and untreated RS with unimodal PSD (Dv50 18.6 & PLUSMN; 0.32 & mu;m) led to higher viscosities and particle settling rates. Biochar morphology and chemical surface constitution significantly influenced slurry stability, while PSD greatly impacted rheological results.