Tuning Benzylic C-H Functionalization of (Thio)xanthenes with Electrochemistry
MOLECULES(2023)
Abstract
Here, we report a tunable electrochemical benzylic C-H functionalization of (thio)xanthenes with terminal alkynes and nitriles in the absence of any catalyst or external chemical oxidant. The benzylic C-H functionalization can be well controlled by varying the electrochemical conditions, affording the specific coupling products via C-C and C-N bond formation.
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Key words
electrochemistry,(thio)xanthenes,benzylic C-H functionalization,alkynes,nitriles
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