Access to Unsaturated Organogermanes Via (de)hydrosilylation Mediated by Cobalt Complexes.

The functionalization of alkynylgermanes using hydrosilanes was accomplished by employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via dehydrogenative coupling or hydrosilylation. Importantly, the presented method is characterized by mild reaction conditions, allowing rapid access to a wide range of organogermanes.