Homocoupling of benzyl pyridyl ethers via visible light-mediated deoxygenation.
Chemical communications (Cambridge, England)(2023)
摘要
The photocatalytic coupling of ethers is uncommon because of the challenges in breaking C-O bonds and low selectivity. Herein, we report a visible light-mediated deoxygenation homocoupling of benzyl pyridyl ethers their pyridium salts. This approach enables C(sp)-O bond homolysis under mild conditions. Mechanistic experiments support the radical nature of the reaction. This method is highly compatible with electron-withdrawing groups and has potential applications for drug precursor synthesis.
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关键词
benzyl pyridyl ethers,light-mediated
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