Coupling surface modification with cocatalyst deposition on BiVO4 photoanode to enhance charge transfer for efficient solar-driven water splitting

Bismuth vanadate (BiVO4) has attracted wide attention as photoanode in water-splitting photoelectrochemical (PEC) devices. However, its catalytic performance is greatly limited by the serious charge recombination on the surface states. Herein, borate modified BiVO4 plus additional CoPi cocatalyst (B-BVO/CoPi) is developed as photoanode for PEC cell via a simple soaking and electrodeposition process. Based on the electrochemistry tests and material characteristics, the borate groups [B(OH)4] -is able to effectively prevent the charge recombination, while the outer CoPi cocatalyst enhance the activity toward oxygen evolution reaction. Therefore, the designed B-BVO/CoPi photoanode could obtain a high current density of 2.67 mA cm-2 at 1.23 VRHE with an onset potential of 0.29 VRHE, much higher than pristine BiVO4 (0.78 mA cm-2, 0.52 VRHE). This work may provide a new insight for constructing multifunctional modified photoanodes for efficient solar conversion. & COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.