Characteristics and mechanism of a persistent ozone pollution event in Pearl River Delta induced by typhoon and subtropical high

Ozone (O3) is a significant air pollutant in the Pearl River Delta (PRD) region, with severe pollution events primarily associated with the Western Pacific Subtropical High (WPSH) and typhoon periphery synoptic weather patterns. To investigate the continuity and differences in O3 pollution processes influenced by these patterns, we analyze a severe O3 pollution event in Zhuhai from September 10 to 13, 2022. The study collects vertical profiles of O3 from the differential absorption O3 lidar and wind fields observed by the Doppler wind profile lidar. We utilize ground-level monitoring data from national ambient air quality monitoring network and meteorological stations to analyze diurnal variations of air pollutant concentrations and ground-level meteorological conditions. The study reveals that both the WPSH and the typhoon periphery create favorable meteorological conditions for severe O3 pollution events. The highest temperatures during the WPSH and typhoon periphery stages are 32.1 °C and 37.5 °C, respectively. During the WPSH control stage, the combined effects of the inversion layer and light static wind hinder O3 dispersion. The ground-level O3 concentration reaches a maximum of 106 ppb. Then the typhoon periphery control stage, the ground-level O3 peak increases to 170 ppb, showing a 60% increase compared to the WPSH stage. O3 horizontal and vertical transport processes play a crucial role in the O3 episode during this stage. The northerly winds predominantly transport pollutants from upstream urban clusters to the local area, and intense downdrafts facilitate the downward transport of O3 from the residual layer. The study investigates the mechanisms of three-dimensional O3 transport within the boundary layer influenced by the WPSH and typhoon periphery in the PRD region. The results contribute valuable insights to pollution events in the PRD region under typical synoptic weather patterns.