Dual Z-scheme TCN/ZnS/ ZnIn2S4 with Efficient Separation for Photocatalytic Nitrogen Fixation.

The development of an efficient catalyst that can use solar energy for NH3 production is of great significance in solving the environmental and energy crisis caused by the traditional ammonia synthesis process. In this work, a dual Z-scheme tubular carbon nitride/zinc sulfide/zinc indium sulfide ternary composited photocatalyst (TCN/ZnS/ZnIn2S4) with excellent nitrogen photofixation performance under visible light was prepared by self-assembly and hydrothermal methods. The crystal structure studies confirmed that tubular carbon nitride (TCN) had more active sites that could promote N2 adsorption. The photochemical studies proved that the double charge transfer channel provided by the dual Z-scheme heterojunction could improve the efficiency of electron-hole separation and achieve excellent photocatalytic nitrogen fixation. The ammonia production rate of the TCN/ZnS/ZnIn2S4 catalyst was up to 136.56 μmol/L, and it also has good stability and reusability. This work provides new insight into the development of Z-scheme heterojunction photocatalysts with green and efficient nitrogen fixation.