Direct Simulation Monte Carlo Modeling of Ammonia in Comet C/2014 Q2 (Lovejoy)

Ammonia (NH _3 ), likely the most abundant nitrogen-bearing molecule in cometary ices followed by hydrogen cyanide, is believed to be stored in the nucleus predominantly as a parent ice. However, spatial profiles of NH _3 observed in comet C/2014 Q2 (Lovejoy) in the near-infrared region are consistent with a distributed source contribution (Dello Russo et al. 2022). We developed the direct simulation Monte Carlo model of ammonia in cometary coma and applied it to comet C/2014 Q2 (Lovejoy). Results suggest that NH _3 molecules in the coma of C/2014 Q2 (Lovejoy) can plausibly originate from a combination of parent molecules of NH _3 in the coma and a NH _3 nucleus source. We demonstrate that the parents of NH _3 having photodissociation lifetimes of several hundreds of seconds or longer (at 1 au from the Sun) can explain the observed spatial profile of NH _3 in comet C/2014 Q2 (Lovejoy). Even though ammonia salts are possible candidates for parents of NH _3 , some simple ammonium salts such as NH _4 CN or NH _4 Cl may dissociate thermally within very short lifetimes after sublimation from the nucleus, so the contribution from those ammonium salts may be indistinguishable from the nucleus source. The lack of experimental data on photoprocesses for potential NH _3 parent molecules prevent us from identifying the origin of NH _3 in comets. Experimental and theoretical studies of photodissociation/ionization reactions of potential NH _3 parent molecules by the solar UV radiation field are encouraged for the future identification of NH _3 parents in comets.