Efficient and fast remediation of soil contaminated by per- and polyfluoroalkyl substances (PFAS) by high-frequency heating

This study presents a novel thermal technology (high-frequency heating, HFH) for the decontamination of soil containing per- and polyfluoroalkyl substances (PFAS) and aqueous film-forming foams (AFFFs). Ultra-fast degradation of short-chain PFAS, long-chain homologs, precursors, legacy PFAS, emerging PFAS was achieved in a matter of minutes. The concentrations of PFAS and the soil type had a negligible impact on degradation efficiency, possibly due to the ultra-fast degradation rate overwhelming potential differences. Under the current HFH experiment setup, we achieved near-complete degradation (e.g., >99.9%) after 1 min for perfluoroalkyl carboxylic acids and perfluoroalkyl ether carboxylic acids and 2 min for perfluoroalkanesulfonic acids. Polyfluoroalkyl precursors in AFFFs were found to degrade completely within 1 min of HFH; no residual cationic, zwitterionic, anionic, or non-ionic intermediate products were detected following the treatment. The gaseous byproducts were considered. Most of gaseous organofluorine products of PFAS at low-and-moderate temperatures disappeared when temperatures reached 890 degrees C, which is in the temperature zone of HFH. For the first time, we demonstrated minimal loss of PFAS in water during the boiling process, indicating a low risk of PFAS entering the atmosphere with the water vapor. The findings highlight HFH its potential as a promising remediation tool for PFAS-contaminated soils.