meso-meso 1,3-bis(E-vinyl) azulene bridged tetrathiaoctaphyrins: Synthesis, Spectroscopic and Theoretical Characterization

Organic chemistry frontiers(2023)

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摘要
Loss of effective dual macrocyclic π-conjugation pathways paving way to strong monocyclic aromaticity with enhanced vis-NIR absorptions of tetrathiaoctaphyrin skeletons via 1,3-bis( E -vinyl)azulene as internal bridging group.
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关键词
tetrathiaoctaphyrins,azulene,meso-meso,e-vinyl
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