Ni-Co Prussian blue analogue/graphene aerogel: a green synthesis approach for high-performance electromagnetic wave absorption and radar stealth applications

JOURNAL OF MATERIALS CHEMISTRY C(2023)

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摘要
Materials for electromagnetic wave (EMW) absorption are rapidly advancing to meet the growing demand for stealth technology and to mitigate electromagnetic pollution. Herein, we innovatively synthesize a superlight Ni-Co Prussian blue analogue microcube/graphene aerogel (Ni-Co PBA/GA) monolith by hydrothermal reaction and freeze-drying. Compared to individual graphene aerogels, Ni-Co PBA/GA displays better impedance matching and multiple mechanisms for attenuating EMWs. Resultantly, Ni-Co PBA/GA presents outstanding EMW absorption performance, whose minimum refection loss is -62.3 dB at 13.3 GHz and the effective absorption bandwidth reaches 5.6 GHz. With the detection Phi of 0 degrees, the simulated radar cross-section reduction of Ni-Co PBA/GA reaches -36.8 dB m2, demonstrating the potential radar-evading ability in the actual far field. Ni-Co PBA/GA may be a promising candidate for a superlight, ecofriendly and high-performance EMW absorption material in the future. A superlight Ni-Co Prussian blue analogue microcube/graphene aerogel is synthesized through a sustainable and ecofriendly route for highly efficient electromagnetic wave absorption.
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