Efficient fabrication and properties of 2D Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2) C-SiC high-entropy ceramic matrix composites via slurry infiltration lamination combined with precursor infiltration and pyrolysis
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY(2023)
摘要
In this work, an efficient processing route was developed to fabricate Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC composites via slurry infiltration lamination (SIL) combined with precursor infiltration and pyrolysis (PIP). The (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C powder was initially synthesized at 1900 degrees C. Then the 2D Cf/ (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC composites were obtained via SIL and PIP at temperatures no higher than 1100 degrees C. The as-fabricated composites show a density of 2.52 g/cm3 and an open porosity of 15.2 vol%, with a bending strength of 255 & PLUSMN; 15 MPa. The 2D Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC composites also present excellent ablation resistance, with the linear and mass recession rates of 0.33 & mu;m/s and 0.60 mg/s after ablation at 2000 degrees C/300 s. This work provides a route for the efficient fabrication of Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC composites, and also inspires new strategies to develop high-entropy ceramic matrix composites with high performance.
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关键词
High-entropy carbides,Composites,Fabrication,Mechanical property,Ablation resistance
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