Interfacial effect between Ni2P/CdS for simultaneously heightening photocatalytic hydrogen production and lignocellulosic biomass photorefining

Photorefining of biomass is increasingly recognized as a pivotal technology for the simultaneous production of hydrogen and value-added chemicals. The intrinsic recalcitrance of lignocellulosic biomass puts high demands on the rational design of bifunctional photocatalyst. Herein, Ni2P/CdS with a strong interfacial effect in this work was designed to overcome lignocellulosic biomass photorefining. The strong interfacial effect between Ni2P and CdS not only improved the light absorbance, but also optimized the spatial redistribution of photogenerated electrons and holes. Therefore, Ni2P/CdS exhibited an unprecedented H2 evolution activity (ca. 199.7 mmol & sdot;h-1 & sdot;g- 1) in the presence of lactic acid as the traditional sacrificial agent. Considerable H2 generation was also achieved in the presence of lignin (ca. 322.8 mu mol & sdot;h-1 & sdot;g- 1), cellulose (ca. 534.3 mu mol & sdot;h-1 & sdot;g-1) and hemi-cellulose (ca. 382.2 mu mol & sdot;h-1 & sdot;g-1) as the electron donor respectively. Theoretical calculation results indicated that establishing the interfacial effect between Ni2P and CdS optimized their work functions. This optimization fosters improved the redistribution between electrons and holes, as a result, photocatalytic hydrogen production from biomass solution was greatly enhanced. Significantly, Ni2P/CdS showed dual functionalities to produce H2 and value-added compounds from raw biomass directly. This present work demonstrates the potential of raw biomass photorefining through astutely designing photocatalysts.