Formation Mechanism of Heavy Hydrocarbon Carbon Isotope Anomalies in Natural Gas from Ordovician Marine Carbonate in the Ordos Basin

Interactive depositional systems of marine carbonates and gypsum salt rocks are closely related to natural gas reservoirs. Despite continuous progress in the exploration of new areas of marine carbonate genesis within the Ordos Basin, the source and mechanism of "sub-salt" natural gas genesis remains controversial. In this study, we investigated natural gas genesis through geochemical analysis of Lower Paleozoic natural gas samples from the mid-eastern Ordos Basin, obtaining natural gas composition data and carbon/hydrogen isotope compositions. We found evident differences between the geochemical characteristics of "sub-salt" and "post-salt" natural gas; the methane carbon isotope signature of "sub-salt" natural gas was lighter overall than that of "post-salt" natural gas, while the ethane carbon isotope composition of the former was more widely distributed and partially lighter than that of the latter. Combining these data with the regional geological background and existing geochemical data, it is evident that Ordovician "post-salt" natural gas comprises a composite of Upper Paleozoic coal-type gas and Lower Paleozoic oil-type gas, with the oil-type gas accounting for the largest proportion. In contrast, the "sub-salt" natural gas was formed and preserved within the Ordovician marine carbonates or sourced from deeper and more ancient hydrocarbon source rocks. Geochemical anomalies, including light methane carbon isotopes and ethane carbon isotopes with coal-type gas characteristics, are closely related to the prevalence of thermochemical sulfate reduction during hydrocarbon formation and reservoir formation of natural gas in "sub-salt" strata.