Quality control of wood treated with citric acid and sorbitol using a handheld Raman spectrometer

Wood modification using polyesterification of sorbitol and citric acid is a novel environmentally friendly strategy for wood protection improving its dimensional stability and acts against fungal deterioration. Inelastic Raman scattering is sensitive to the molecules of high polarizability and both lignocellulose and aliphatic esters formed during the treatment are polar. Therefore, in the present study, the quality control of the treatment using a handheld Raman spectrometer equipped with 830 nm laser is suggested as a rapid and reliable approach. Raman spectra from six wood modification levels (resulting in different weight percent gain, WPG) of three different wood species (Silver birch, Scots pine and Norway spruce) as well as three sample preparation strategies (intact, sanded and milled wood samples) were collected, and further analyzed using a chemometric method. Best performing models based on Powered Partial Least Squares Regression predicted the WPG level at R2 = 0.85, 0.95 and 0.98 for birch, pine and spruce, respectively. In addition, a clear separation between hard and soft wood species was also captured. Especially for softwood species, the sample preparation method affected the model accuracy, revealing the best performance in milled material. It is concluded that by using handheld Raman spectrometer it is possible to perform accurate quality control of wood modified by polyesterification of citric acid and sorbitol.