Regulating the Coordination Environment of Mesopore‐Confined Single Atoms from Metalloprotein‐MOFs for Highly Efficient Biocatalysis (Adv. Mater. 44/2022)

Single-Atom Catalysts In article number 2205674, Kang Liang and co-workers develop a generalized strategy to construct highly active ferric-centered single-atom catalysts via a biomineralization strategy that enables the homogeneous encapsulation of metalloproteins within metal-organic frameworks followed by pyrolysis. The enhanced activity of the obtained catalysts benefits from the highly dispersed atoms, the mesopores, and the regulated coordination environment of the single-atom active sites induced by the metalloproteins.