Visible light-induced gem-difluoroallylation of [1.1.1]propellane to access gem-difluoroallylic bicyclo[1.1.1]pentanes

Hui Zhu, Shengxing Wu,Bingbin Zhu,Jiacheng Li,Deyou Lan,Wenhao Xu,Gongcheng Xu,Yu Zhu,Chuanming Yu,Xinpeng Jiang

Chemical Communications（2023）

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摘要

gem -Difluoroallylic bicyclo[1.1.1]pentanes were synthesized via visible light-induced defluorinative gem -difluoroallylation of [1.1.1]propellane under mild conditions with good functional group tolerance.

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light-induced

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