Atmospheric chemistry of (Z)- and (E)-1,2-dichloroethene: kinetics and mechanisms of the reactions with Cl atoms, OH radicals, and O₃

Mads Peter Andersen,Αleksandra Volkova,Sofie Askjær Hass,Jonathan Wilson Lengkong,Dvien Hovanessian,Theis I. Sølling,T.J. Wallington,Ole John Nielsen

Physical Chemistry Chemical Physics（2022）

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摘要

A comprehensive experimental study of the atmospheric chemistry of ( Z )- and ( E )-CHClCHCl. The compounds have short atmospheric lifetimes, low photochemical ozone creation potentials, and show a substantial Cl-elimination pathway for the OH-adduct.

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atmospheric chemistry,cl atoms,reactions

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Atmospheric chemistry of (Z)- and (E)-1,2-dichloroethene: kinetics and mechanisms of the reactions with Cl atoms, OH radicals, and O3

Atmospheric chemistry of (Z)- and (E)-1,2-dichloroethene: kinetics and mechanisms of the reactions with Cl atoms, OH radicals, and O₃