Azulene-Fused Linearly -Extended Polycyclic Aromatic Compounds: Synthesis, Photophysical Properties, and OFETs Applications

Masahito Murai, Shinji Iba,Sh ino Hamao,Yoshihiro Kubozono,Hiromi Ota, Kazuh iko Taka

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN（2023）

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摘要

By introducing azulene into linearly pi-extended polycyclic aromatic hydrocarbons, we found that the HOMO-LUMO gap can be narrowed comparable to [n]acenes while affording high stability against air under visible light. The fabricated OFET devices with one of the derivatives exihibited typical p-type behavior under ambient conditions.

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关键词

polycyclic aromatic compounds,photophysical properties,azulene-fused

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