Evaluation of the performance of a ${}^{40}\textrm{Ca}^+ - {}^{27}\textrm{Al}^+$ optical clock

We report the evaluation of the systematic shifts and the total uncertainty of an ${}^{27}\textrm{Al}^+$ optical clock sympathetically cooled by a ${}^{40}\textrm{Ca}^+$ ion. Due to its relatively low Doppler cooling limit and the suitability of its mass ratio to the ${}^{27}\textrm{Al}^+$ ion, the time dilation shift of the secular motion of our ${}^{40}\textrm{Ca}^+ - {}^{27}\textrm{Al}^+$ clock is smaller than the shift of a ${}^{25}\textrm{Mg}^+ - {}^{27}\textrm{Al}^+$ clock. The total systematic uncertainty of our ${}^{40}\textrm{Ca}^+ - {}^{27}\textrm{Al}^+$ quantum logic clock has been estimated to be $7.6 \times 10^{-18}$, which was mainly limited by the uncertainty of the quadratic Zeeman shift.