Assembly of unsymmetrical 1,3,5-triarylbenzenes via tandem reaction of β-arylethenesulfonyl fluorides and α-cyano-β-methylenones

Fang Zhang,Yi An,Jichang Liu, Gangjun Du,Zhihua Cai,Lin He

New Journal of Chemistry（2022）

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摘要

A transition-metal-free method has been proposed for the synthesis of unsymmetrical 1,3,5-triarylbenzenes via a tandem Diels–Alder cycloaddition/SuFEx/elimination process.

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tandem reaction

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