Microstructure Characterization and Hardening Evaluation of Ferrite/Martensitic Steels Induced by He2+ Irradiation

Two ferrite/martensitic (F/M) steels with different Si concentrations (0 and 0.4 wt.%) were irradiated by 250 keV He2+ ions with different fluences of 2 × 1016 ions/cm2 and 1 × 1017 ions/cm2. Transmission electron microscopy and a nanoindenter were employed to investigate their microstructure evolution and irradiation hardening effects induced by high-energy He2+ ions. A large number of He bubbles formed in the Si-free and Si-containing F/M steels, which preferentially nucleated and grew at the lath and phase boundaries. Owing to the inhibiting effect of Si addition on He bubble growth, the He bubbles in the Si-containing sample exhibited smaller size and higher density at the same He2+ fluence. Nanoindenter measurement revealed that typical irradiation hardening was observed in the F/M steel, and 1/2<111> and <100> type dislocation loops formed by He2+ irradiation was recognized as the dominant mechanism. The addition of Si induced an increase in the number density of dislocation loops, leading to the exacerbation of the irradiation hardening, and the results are basically in agreement with the theoretical analysis based on the dispersion barrier hardening (DBH) and Friedel–Kroupa–Hirsch (FKH) models.