Phase dependence and mechano and thermal ductility of the luminescence properties of tetranuclear Cu(I) metallacycle assemblies stabilized by ditopic organo-pnictogen (P, As) ligands.

Christophe Lescop,Guillaume Calvez,Karine Costuas,Manfred Scheer,Constance Lecourt,Raquel Utrera-Melero,Jana Schiller,Vincent Dorcet,Florent Moutier,Corentin Poidevin

Inorganic chemistry frontiers（2023）

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摘要

A tetranuclear Cu( i ) metallacycle stabilized by ditopic organo-pnictogen (P,As) ligands presents stimuli-sensitive luminescence whose origin is compared with those based on congener (P,P) ligands, revealing competitive effects involving solid-state packing and spin–orbit coupling.

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关键词

metallacycle assemblies,ligands,luminescence properties,cui,organo-pnictogen

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