A Rh-catalyzed isomerization of 1-alkenes to (E)-2-alkenes: from a homogeneous Rh/PPh₃ catalyst to a heterogeneous Rh/POP-PPh₃-SO₃Na catalyst

Xiaofei Jia,Ziqi Liu,Jiaxin Song,Yushuang Zhang,Shuhui Sun, Zhe Kun,Jianbin Chen,Congxia Xie

Catalysis Science & Technology（2023）

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摘要

An efficient homogeneous Rh/PPh 3 catalyst and a reusable heterogeneous Rh/POP-PPh 3 -SO 3 Na catalyst have been developed for the isomerization of 1-alkenes to ( E )-2-alkenes, respectively.

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catalyst,heterogeneous rh-catalyzed,isomerization,pop-pph

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A Rh-catalyzed isomerization of 1-alkenes to (E)-2-alkenes: from a homogeneous Rh/PPh3 catalyst to a heterogeneous Rh/POP-PPh3-SO3Na catalyst

A Rh-catalyzed isomerization of 1-alkenes to (E)-2-alkenes: from a homogeneous Rh/PPh₃ catalyst to a heterogeneous Rh/POP-PPh₃-SO₃Na catalyst