Tweaking the bridge in metallocene Zr(iv)/W(iv) bimetallic hydrides

Selwin Fernando,Martina Landrini,Alceo Macchioni,David L. Hughes,Peter H. M. Budzelaar,Luca Rocchigiani

Dalton Transactions（2023）

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摘要

σ-Bond metathesis between zirconocene cations and Cp 2 WH 2 affords a bimetallic bridging hydride with an out of plane configuration and no M–M interaction. Small molecules react predominantly at the Zr-C bond in the absence of bimetallic cooperativity.

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关键词

bimetallic hydrides,bridge

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