Catalytic Oxidation of CO over LaNi 1/3 Sb 5/3 O 6 Synthesized by Different Methods

A. V. Egorysheva,S. V. Golodukhina,K. R. Plukchi,E. Yu. Liberman,O. G. Ellert,A. V. Naumkin,A. V. Chistyakov,I. V. Kolesnik,O. V. Arapova

Russian journal of inorganic chemistry（2023）

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摘要

Methods for the synthesis of LaNi1/3Sb5/3O6 with a rosiaite structure have been developed using citrate method and coprecipitation followed by annealing. The influence of synthesis conditions on the morphology of the samples has been demonstrated. A comparative analysis of the catalytic properties of LaNi1/3Sb5/3O6 synthesized by various methods, in the reaction of CO oxidation has been carried out. The catalyst synthesized by the citrate method demonstrated the greatest efficiency and stability (the temperature of 90

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complex nickel oxide,rosiaite,coprecipitation,citrate synthesis,XPS,in situ diffuse reflectance IR spectra,O2-TPD

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