Facile access to thieno[2,3-b]thiophenes and poly-substituted thiophenes through divergent annulation of ketene 1,3-dithietanes
ORGANIC CHEMISTRY FRONTIERS(2024)
摘要
A Lewis acid-catalyzed tandem nucleophilic addition/C-S cleavage/intramolecular annulation of ketene 1,3-dithietanes with aldehydes and photo-induced cycloaddition of ketene 1,3-dithietanes with alkynes were developed in this work. The readily available ketene 1,3-dithietanes were demonstrated as promising sulfur-containing synthons for the facile construction of the thiophene ring. Moreover, these processes feature simple operation, good functional group tolerance and mild reaction conditions. Also, the possible mechanisms are proposed in this study.
更多查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要